The awning light should be fed from Circuit 5 (fused at 7.5A) but it really doesn't matter if it's fed from one of the other circuits, 1, 2 or 3.
Circuit 4 doesn't seem to feature in the documentation, but I guess it's the pump circuit.
All circuits, with the exception of the fridge low current supply, will disconnect when either the 12V switch is toggled to off, or the car ignition is switched on (with the 13 pin plug connected to the towcar).
So yes - you can connect your TV to circuit 5 - although you won't be able to watch it when you're towing
European harmonised cable colours for ELV circuits (the 12V dc side of things) are indeed blue for +12V and brown for 0V.
Your TV's 12V input cable could possible be as above but more than likely red and black.